Inorganic and Organometallic Chemistry
نویسندگان
چکیده
The activities of the group comprise the synthesis, characterization and reactivity studies of inorganic, organometallic and intermetallic compounds of actinides and lanthanides in order to understand the influence of the electronic configuration and of the size of these elements in the chemical behaviour of their compounds. Reactivity properties are assessed by stoichiometric reactions and by homogeneous and heterogeneous catalytic studies. Gas phase ion-molecule reactions with the same elements and the study of the energetics of f-element compounds are also made with the same objective.
منابع مشابه
Hybrid Organometallic-Inorganic Nanomaterial: Acetyl Ferrocene Schiff base Immobilized on Silica Coated Magnetite Nanoparticles
In this work, a new hybrid organometallic-inorganic hybrid nanomaterial was prepared by immobilization of acetyl ferrocene on the surface of magnetite nanoparticles. Covalent grafting of silica coated magnetite nanoparticles (SCMNPs) with 3-aminopropyl triethoxysilane gave aminopropyl-modified magnetite nanoparticles (AmpSCMNPs). Then, Schiff base condensation of AmpSCMNPs with acet...
متن کاملMedicinal organometallic chemistry: designing metal arene complexes as anticancer agents.
The field of medicinal inorganic chemistry is rapidly advancing. In particular organometallic complexes have much potential as therapeutic and diagnostic agents. The carbon-bound and other ligands allow the thermodynamic and kinetic reactivity of the metal ion to be controlled and also provide a scaffold for functionalization. The establishment of structure-activity relationships and elucidatio...
متن کاملOrganometallic chemistry
This Thematic Series is dedicated to the memory of Professor Peter Hofmann (Figure 1) whose research work included many seminal contributions to the field of organometallic chemistry [1-3]. Organometallic chemistry has therefore been chosen as the topic of this Thematic Series of the Beilstein Journal of Organic Chemistry. Over a period of many decades, the chemistry of metal–carbon bonds has g...
متن کاملPlatinum-oxygen Bond Formation: Kinetic and Mechanistic Studies
Reaction of [PtMe(C^N)(SMe2)] (C^N = 2-phenylpyridinate (ppy); 1a, C^N = benzo[h]quinolate, (bhq); 1b) with hydrogen peroxide gives the platinum(IV) complexes trans-[PtMe(OH)2(C^N)(H2O)] (C^N = ppy; 3a, C^N = bhq, 3b) bearing platinum-oxygen bonds. The Pt(II) complexes 1a and 1b have 5dπ(Pt)→π*(C^N) MLCT band in the visible region which is used to easily follow the kinetic of its reaction with ...
متن کاملCHEM3012 - Core Chemistry 3 Inorganic Reaction Mechanisms
The substitution of ligands in octahedral metal complexes is the most extensively mechanistically studied inorganic reaction. It is of fundamental importance, and a number of important observations and results are found. Substitution in octahedral systems was initially studied for classical coordination complexes in aqueous solutions. More recently some important observations have been made reg...
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